Pentachlorophenol monooxygenase: pentachlorophenol + NADPH + dioxygen + H+→2,3,5,6-tetrachloro-1,4-benzoquinone + chloride + NADP+ + H2O (EC 1.14.13.50) |
No genes |
2,3,5,6-tetrachloro-1,4-benzoquinone + NADH→2,3,5,6-tetrachlorohydroquinone + NAD+ + H+ (EC 1.1.1.404) |
No genes |
2,3,5,6-tetrachlorohydroquinone + glutathione + H+→2,3,5-trichloro-6-(glutathion-S-yl)-hydroquinone + chloride (EC 1.21.4.5; 2.5.1.18) |
mRNA_2551 (10919) |
mRNA_2565 (10933) |
mRNA_3446 (11814) |
mRNA_8382 (16750) |
mRNA_420 (8788) |
mRNA_421 (8789) |
mRNA_546 (8914) |
2,3,5-trichloro-6-(glutathion-S-yl)-hydroquinone + glutathione→2,3,6-trichlorohydroquinone + glutathione disulfide + H+ (EC 1.21.4.5; 1.8.5.7) |
No genes |
2,3,6-trichlorohydroquinone + glutathione→2,6-dichloro-3-(glutathion-S-yl)-hydroquinone + chloride (EC 1.21.4.5; 2.5.1.18) |
mRNA_2551 (10919) |
mRNA_2565 (10933) |
mRNA_3446 (11814) |
mRNA_8382 (16750) |
mRNA_420 (8788) |
mRNA_421 (8789) |
mRNA_546 (8914) |
2,6-dichloro-3-(glutathion-S-yl)-hydroquinone + glutathione→2,6-dichlorohydroquinone + glutathione disulfide + H+ (EC 1.21.4.5; 1.8.5.7) |
No genes |
2,6-dichlorohydroquinone + dioxygen + H2O→2-chloromaleylacetate + chloride + 2 H+ |
No genes |
Maleylacetate reductase (in reverse): 2-chloromaleylacetate + NAD(P)H + H+→5-chloro-3-oxoadipate + NAD(P)+ (EC 1.3.1.32) |
mRNA_3939 (12307) |
5-chloro-3-oxoadipate→2-maleylacetate + chloride + H+ (spontaneous) |
No genes |
Maleylacetate reductase (in reverse): 2-maleylacetate + NAD(P)H + H+→3-oxoadipate + NAD(P)+ (EC 1.3.1.32) |
mRNA_3939 (12307) |
mRNA_733 (9101) |
Links:
Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information