MetaCyc Pathway: suberin monomers biosynthesis in Rhodosporidium toruloides IFO0880

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Palmitoyl-CoA hydrolase:
palmitoyl-CoA + H2O→palmitate + coenzyme A + H+ (EC 3.1.2.2)
No genes
Phenylalanine ammonia-lyase:
L-phenylalanine→cinnamate + ammonium (EC 4.3.1.24; 4.3.1.25; 5.4.3.10)
mRNA_8094 (16462)
docosanoyl-CoA + dioxygen + a reduced [NADPH-hemoprotein reductase]→22-hydroxy-docosanoyl-CoA + an oxidized [NADPH-hemoprotein reductase] + H2O
No genes
Palmitoyl-CoA hydrolase:
oleoyl-CoA + H2O→oleate + coenzyme A + H+ (EC 3.1.2.2)
No genes
22-hydroxy-docosanoyl-CoA + NADP+→22-oxo-docosanoyl-CoA + NADPH + H+
No genes
palmitate + dioxygen + a reduced [NADPH-hemoprotein reductase]→16-hydroxypalmitate + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.80)
No genes
oleate + dioxygen + a reduced [NADPH-hemoprotein reductase]→18-hydroxyoleate + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.80)
No genes
cinnamate + dioxygen + a reduced [NADPH-hemoprotein reductase]→4-coumarate + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.91)
No genes
4-coumarate + dioxygen + a reduced [NADPH-hemoprotein reductase]→trans-caffeate + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.96)
No genes
22-oxo-docosanoyl-CoA + NADP+ + H2O→22-carboxy-docosanoyl-CoA + NADPH + 2 H+
No genes
Long-chain-fatty-acid--CoA ligase:
16-hydroxypalmitate + ATP + coenzyme A→16-hydroxypalmitoyl-CoA + AMP + diphosphate (EC 6.2.1.3)
mRNA_4187 (12555)
mRNA_7380 (15748)
18-hydroxyoleate + NADP+→18-oxo-oleate + NADPH + H+
No genes
Caffeate O-methyltransferase:
trans-caffeate + S-adenosyl-L-methionine→ferulate + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.68)
No genes
4-coumarate--CoA ligase:
trans-caffeate + ATP + coenzyme A→(E)-caffeoyl-CoA + AMP + diphosphate (EC 6.2.1.12)
No genes
22-carboxy-docosanoyl-CoA + sn-glycerol 3-phosphate→2-C22:0-DCA-LPA + coenzyme A (EC 2.3.1.198)
No genes
18-oxo-oleate + NADP+ + H2O→α,ω-9Z-octadecenedioate + NADPH + 2 H+
No genes
Trans-feruloyl-CoA synthase:
ferulate + ATP + coenzyme A→feruloyl-CoA + AMP + diphosphate (EC 6.2.1.34)
No genes
Caffeoyl-CoA O-methyltransferase:
(E)-caffeoyl-CoA + S-adenosyl-L-methionine→feruloyl-CoA + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.104)
No genes
Long-chain-fatty-acid--CoA ligase:
α,ω-9Z-octadecenedioate + ATP + coenzyme A→ω-carboxy-(9Z)-octadec-9-enoyl-CoA + AMP + diphosphate (EC 6.2.1.3)
mRNA_4187 (12555)
mRNA_7380 (15748)
Tyramine N-feruloyltransferase:
feruloyl-CoA + tyramine→N-feruloyltyramine + coenzyme A + H+ (EC 2.3.1.110)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information