MetaCyc Pathway: superpathway of benzoxazinoid glucosides biosynthesis in Rhodosporidium toruloides IFO0880

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Indole-3-glycerol-phosphate lyase:
(1S,2R)-1-C-(indol-3-yl)glycerol 3-phosphate→indole + D-glyceraldehyde 3-phosphate (EC 4.1.2.8; 4.2.1.20)
mRNA_894 (9262)
indole + dioxygen + a reduced [NADPH-hemoprotein reductase]→indolin-2-one + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.153)
No genes
indolin-2-one + dioxygen + a reduced [NADPH-hemoprotein reductase]→3-hydroxyindolin-2-one + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.157)
No genes
3-hydroxyindolin-2-one + dioxygen + a reduced [NADPH-hemoprotein reductase]→HBOA + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.109)
No genes
HBOA + dioxygen + a reduced [NADPH-hemoprotein reductase]→DIBOA + an oxidized [NADPH-hemoprotein reductase] + H+ + H2O (EC 1.14.14.110)
No genes
glucosyltransferase:
DIBOA + UDP-α-D-glucose→DIBOA-β-D-glucoside + UDP (EC 2.4.1.202)
No genes
DIBOA-β-D-glucoside + S-adenosyl-L-methionine→4-O-methyl-DIBOA-glucoside + S-adenosyl-L-homocysteine + H+
No genes
DIBOA-β-D-glucoside + 2-oxoglutarate + dioxygen→TRIBOA-β-D-glucoside + CO2 + succinate (EC 1.14.11.59)
No genes
TRIBOA-β-D-glucoside + S-adenosyl-L-methionine→DIMBOA-β-D-glucoside + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.241)
No genes
DIMBOA-β-D-glucoside + 2-oxoglutarate + dioxygen→TRIMBOA-β-D-glucoside + CO2 + succinate (EC 1.14.11.M27)
No genes
DIMBOA-β-D-glucoside + S-adenosyl-L-methionine→HMDBOA-glucoside + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.M65)
No genes
TRIMBOA-β-D-glucoside + S-adenosyl-L-methionine→DIM2BOA-β-D-glucoside + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.M64)
No genes
DIM2BOA-β-D-glucoside + S-adenosyl-L-methionine→HDM2BOA-glucoside + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.M65)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information