MetaCyc Pathway: coumarin biosynthesis (via 2-coumarate) in Rhodosporidium toruloides IFO0880

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Trans-cinnamate 2-monooxygenase:
cinnamate + NADPH + dioxygen + H+→trans-2-coumarate + NADP+ + H2O (EC 1.14.13.14)
No genes
2-coumarate O-beta-glucosyltransferase:
trans-2-coumarate + UDP-α-D-glucose→2-O-(β-D-glucosyl)-2-hydroxycinnamate + H+ + UDP (EC 2.4.1.114)
No genes
2-O-(β-D-glucosyl)-2-hydroxycinnamate→cis-coumarinic acid-β-D-glucoside
No genes
Beta-glucosidase:
cis-coumarinic acid-β-D-glucoside + H2O→coumarinate + D-glucopyranose (EC 3.2.1.21)
mRNA_5118 (13486)
mRNA_8348 (16716)
mRNA_8349 (16717)
mRNA_160 (8528)
mRNA_1271 (9639)
coumarinate + H+→coumarin + H2O (spontaneous)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information