MetaCyc Pathway: traumatin and (Z)-3-hexen-1-yl acetate biosynthesis in Rhodosporidium toruloides IFO0880

Add experiment(s):


Lipoxygenase:
linoleate + dioxygen→(13S)-HPODE
(EC 1.13.11.12)
No genes
Lipoxygenase:
α-linolenate + dioxygen→13(S)-HPOTE
(EC 1.13.11.12)
No genes
(13S)-HPODE→(9Z)-12-oxo-dodec-9-enoate + 1-hexanal (EC 4.2.1.M17; 4.2.1.M19)
No genes
13(S)-HPOTE→(9Z)-12-oxo-dodec-9-enoate + (3Z)-hexenal (EC 4.2.1.M17; 4.2.1.M19)
No genes
(3Z)-hexenal→(E)-2-hexenal (spontaneous)
No genes
(3Z)-hexenal + NADH + H+→(3Z)-hex-3-en-1-ol + NAD+
No genes
(9Z)-12-oxo-dodec-9-enoate→traumatin
No genes
(3Z)-hex-3-en-1-ol + acetyl-CoA→(3Z)-hex-3-en-1-yl acetate + coenzyme A (EC 2.3.1.195)
No genes
Alcohol dehydrogenase (NADP(+)) (in reverse):
(E)-2-hexenal + NADPH + H+→(E)-2-hexenol + NADP+
(EC 1.1.1.2)
mRNA_1661 (10029)
mRNA_6332 (14700)

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information