MetaCyc Pathway: GDP-L-colitose biosynthesis in Rhodosporidium toruloides IFO0880

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GDP-mannose 4,6-dehydratase:
GDP-α-D-mannose→GDP-4-dehydro-α-D-rhamnose + H2O (EC 4.2.1.47)
mRNA_2621 (10989)
mRNA_3255 (11623)
GDP-4-dehydro-α-D-rhamnose + L-glutamate→2-GDP-[(2S,3S,6R)-5-amino-6-methyl-3,6-dihydro-2H-pyran-3-ol] + 2-oxoglutarate + H+ + H2O (EC 4.2.1.168)
No genes
2-GDP-[(2S,3S,6R)-5-amino-6-methyl-3,6-dihydro-2H-pyran-3-ol] + H+→2-GDP-[(2S,3S,6R)-5-imino-6-methyloxan-3-ol] (spontaneous) (EC 4.2.1.168)
No genes
2-GDP-[(2S,3S,6R)-5-imino-6-methyloxan-3-ol] + H2O→GDP-4-dehydro-3,6-dideoxy-α-D-mannose + ammonium (spontaneous) (EC 4.2.1.168)
No genes
GDP-4-dehydro-3,6-dideoxy-α-D-mannose + NAD(P)H + H+→GDP-β-colitose + NAD(P)+ (EC 1.1.1.356)
No genes

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information