MetaCyc Pathway: ubiquinol-7 biosynthesis (late decarboxylation) in Rhodosporidium toruloides IFO0880

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4-hydroxybenzoate nonaprenyltransferase:
4-hydroxybenzoate + all-trans-heptaprenyl diphosphate→4-hydroxy-3-heptaprenylbenzoate + diphosphate (EC 2.5.1.39)
mRNA_6869 (15237)
4-hydroxy-3-heptaprenylbenzoate + NADPH + dioxygen + H+→3,4-dihydroxy-5-all-trans-heptaprenylbenzoate + NADP+ + H2O (EC 1.14.13.M81)
No genes
Hexaprenyldihydroxybenzoate methyltransferase:
3,4-dihydroxy-5-all-trans-heptaprenylbenzoate + S-adenosyl-L-methionine→3-methoxy-4-hydroxy-5-all-trans-heptaprenylbenzoate + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.114)
No genes
3-methoxy-4-hydroxy-5-all-trans-heptaprenylbenzoate + H+→2-methoxy-6-(all-trans-heptaprenyl)phenol + CO2
No genes
2-methoxy-6-(all-trans-heptaprenyl)phenol + NADPH + dioxygen + H+→2-methoxy-6-all trans-heptaprenyl-1,4-benzoquinol + NADP+ + H2O (EC 1.14.13.M56)
No genes
2-methoxy-6-all trans-heptaprenyl-1,4-benzoquinol + S-adenosyl-L-methionine→6-methoxy-3-methyl-2-all-trans-heptaprenyl-1,4-benzoquinol + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.201)
No genes
6-methoxy-3-methyl-2-all-trans-heptaprenyl-1,4-benzoquinol + a reduced unknown two electron carrier + dioxygen→3-demethylubiquinol-7 + an oxidized unknown electron carrier + H2O (EC 1.14.99.60)
No genes
3-demethylubiquinone-9 3-O-methyltransferase:
3-demethylubiquinol-7 + S-adenosyl-L-methionine→ubiquinol-7 + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.64)
mRNA_3097 (11465)

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information