MetaCyc Pathway: sorgoleone biosynthesis in Rhodosporidium toruloides IFO0880

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Stearoyl-CoA 9-desaturase:
palmitoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→palmitoleoyl-CoA + 2 a ferricytochrome b5 + 2 H2O
(EC 1.14.19.1)
mRNA_1362 (9730)
Delta(12)-fatty-acid desaturase:
palmitoleoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(9Z,12Z)-hexadeca-9,12-dienoyl-CoA + 2 a ferricytochrome b5 + 2 H2O
(EC 1.14.19.6)
No genes
(9Z,12Z)-hexadeca-9,12-dienoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(9Z,12Z,15Z)-hexadeca-9,12,15-trienoyl-CoA + 2 a ferricytochrome b5 + 2 H2O (EC 1.14.19.13)
No genes
(9Z,12Z,15Z)-hexadeca-9,12,15-trienoyl-CoA + 3 malonyl-CoA + 3 H+→5-pentadecatrienyl resorcinol + 4 CO2 + 4 coenzyme A
No genes
5-pentadecatrienyl resorcinol + S-adenosyl-L-methionine→5-pentadecatrienyl resorcinol-3-methyl ether + S-adenosyl-L-homocysteine + H+
No genes
1.-.-.-:
5-pentadecatrienyl resorcinol-3-methyl ether + a reduced unknown two electron carrier + dioxygen→dihydrosorgoleone + an oxidized unknown electron carrier + H2O
No genes
dihydrosorgoleone + a methylated methyl donor→methoxydihydrosorgoleone + a demethylated methyl donor
No genes
dihydrosorgoleone + dioxygen→sorgoleone + H+ + H2O
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information