MetaCyc Pathway: benzoate biosynthesis I (CoA-dependent, β-oxidative) in Rhodosporidium toruloides IFO0880

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Phenylalanine ammonia-lyase:
L-phenylalanine→cinnamate + ammonium (EC 4.3.1.24; 4.3.1.25; 5.4.3.10)
mRNA_8094 (16462)
cinnamate + ATP + coenzyme A→cinnamoyl-CoA + AMP + diphosphate
No genes
cinnamoyl-CoA + H2O→3-hydroxy-3-phenylpropanoyl-CoA
No genes
3-hydroxy-3-phenylpropanoyl-CoA + NADP+→3-oxo-3-phenylpropanoyl-CoA + NADPH + H+
No genes
3-oxo-3-phenylpropanoyl-CoA + coenzyme A→benzoyl-CoA + acetyl-CoA
No genes
benzoyl-CoA + H2O→benzoate + coenzyme A + H+
No genes
Benzoate--CoA ligase:
benzoate + ATP + coenzyme A→benzoyl-CoA + AMP + diphosphate (EC 6.2.1.25)
No genes
benzoyl-CoA + benzyl alcohol→benzylbenzoate + coenzyme A (EC 2.3.1.196)
No genes
benzylbenzoate + H2O→benzoate + benzyl alcohol + H+
No genes

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information