MetaCyc Pathway: fluoroacetate and fluorothreonine biosynthesis in Rhodosporidium toruloides IFO0880

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Adenosyl-fluoride synthase:
fluoride + S-adenosyl-L-methionine→5'-deoxy-5'-fluoroadenosine + L-methionine (EC 2.5.1.63)
No genes
Purine-nucleoside phosphorylase:
5'-deoxy-5'-fluoroadenosine + phosphate→5-fluoro-5-deoxy-D-ribose 1-phosphate + adenine (EC 2.4.2.1)
mRNA_7908 (16276)
5-fluoro-5-deoxy-D-ribose 1-phosphate→5-fluoro-5-deoxy-D-ribulose 1-phosphate
No genes
5-fluoro-5-deoxy-D-ribulose 1-phosphate→fluoroacetaldehyde + glycerone phosphate
No genes
Fluoroacetaldehyde dehydrogenase:
fluoroacetaldehyde + NAD+ + H2O→fluoroacetate + NADH + 2 H+ (EC 1.2.1.69)
No genes
Fluorothreonine transaldolase:
fluoroacetaldehyde + L-threonine→4-fluorothreonine + acetaldehyde (EC 2.2.1.8)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information