MetaCyc Pathway: 4-hydroxyacetophenone degradation in Rhodosporidium toruloides IFO0880

Add experiment(s):


4-hydroxyacetophenone monooxygenase:
4-hydroxyacetophenone + NADPH + dioxygen + H+→4-acetoxyphenol + NADP+ + H2O (EC 1.14.13.84)
No genes
4-acetoxyphenol + H2O→hydroquinone + acetate + H+
No genes
hydroquinone + dioxygen→(2Z,4E)-4-hydroxy-6-oxohexa-2,4-dienoate + H+ (EC 1.13.11.66)
No genes
4-hydroxymuconic-semialdehyde dehydrogenase:
(2Z,4E)-4-hydroxy-6-oxohexa-2,4-dienoate + NAD+ + H2O→2-maleylacetate + NADH + 2 H+ (EC 1.2.1.61)
No genes
Maleylacetate reductase (in reverse):
2-maleylacetate + NAD(P)H + H+→3-oxoadipate + NAD(P)+ (EC 1.3.1.32)
mRNA_3939 (12307)
mRNA_733 (9101)

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information