MetaCyc Pathway: hyperxanthone E biosynthesis in Rhodosporidium toruloides IFO0880

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Phenylalanine ammonia-lyase:
L-phenylalanine→cinnamate + ammonium
(EC 4.3.1.24; 4.3.1.25; 5.4.3.10)
mRNA_8094 (16462)
cinnamate + ATP + coenzyme A→cinnamoyl-CoA + AMP + diphosphate
No genes
cinnamoyl-CoA + H2O→3-hydroxy-3-phenylpropanoyl-CoA
No genes
3-hydroxy-3-phenylpropanoyl-CoA + NADP+→3-oxo-3-phenylpropanoyl-CoA + NADPH + H+
No genes
3-oxo-3-phenylpropanoyl-CoA + coenzyme A→benzoyl-CoA + acetyl-CoA
No genes
benzoyl-CoA + 3 malonyl-CoA + 3 H+→2,4,6-trihydroxybenzophenone + 3 CO2 + 4 coenzyme A (EC 2.3.1.220)
No genes
2,4,6-trihydroxybenzophenone + prenyl diphosphate→hyperxanthone E + diphosphate
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information