MetaCyc Pathway: terrequinone A biosynthesis in Rhodosporidium toruloides IFO0880

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Tryptophan--phenylpyruvate transaminase:
L-tryptophan + 3-phenyl-2-oxopropanoate→(indol-3-yl)pyruvate + L-phenylalanine
(EC 2.6.1.28)
mRNA_4039 (12407)
2 (indol-3-yl)pyruvate + 2 ATP→didemethylasterriquinone D + 2 AMP + 2 diphosphate
No genes
didemethylasterriquinone D + prenyl diphosphate→asterriquinone C1 + diphosphate
No genes
didemethylasterriquinone D + 2 NADH→hydrodidemethylasterriquinone D + 2 NAD+
No genes
asterriquinone C1→terrequinone A
No genes
hydrodidemethylasterriquinone D + an oxidized unknown electron carrier + prenyl diphosphate + 2 H+→ochrindole D + a reduced unknown two electron carrier + diphosphate + H2O
No genes
ochrindole D + prenyl diphosphate→terrequinone A + diphosphate
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information