MetaCyc Pathway: stellatic acid biosynthesis in Rhodosporidium toruloides IFO0880

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Dimethylallyltranstransferase:
prenyl diphosphate + 3-methylbut-3-en-1-yl diphosphate→geranyl diphosphate + diphosphate
(EC 2.5.1.1)
mRNA_4576 (12944)
mRNA_8135 (16503)
Geranyltranstransferase:
geranyl diphosphate + 3-methylbut-3-en-1-yl diphosphate→(2E,6E)-farnesyl diphosphate + diphosphate
(EC 2.5.1.10)
mRNA_4576 (12944)
mRNA_8135 (16503)
Farnesyltranstransferase:
(2E,6E)-farnesyl diphosphate + 3-methylbut-3-en-1-yl diphosphate→geranylgeranyl diphosphate + diphosphate
(EC 2.5.1.29)
mRNA_8135 (16503)
geranylgeranyl diphosphate + 3-methylbut-3-en-1-yl diphosphate→geranylfarnesyl diphosphate + diphosphate (EC 2.5.1.81)
No genes
geranylfarnesyl diphosphate→stellata-2,6,19-triene + diphosphate (EC 4.2.3.178)
No genes
stellata-2,6,19-triene + dioxygen + a reduced [NADPH-hemoprotein reductase]→stellatic alcohol + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.M35)
No genes
stellatic alcohol + dioxygen + a reduced [NADPH-hemoprotein reductase]→stellatic aldehyde + an oxidized [NADPH-hemoprotein reductase] + 2 H2O (EC 1.14.14.M35)
No genes
stellatic aldehyde + dioxygen + a reduced [NADPH-hemoprotein reductase]→stellatate + an oxidized [NADPH-hemoprotein reductase] + H+ + H2O (EC 1.14.14.M35)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information