MetaCyc Pathway: roseoflavin biosynthesis in Rhodosporidium toruloides IFO0880

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Riboflavin kinase:
riboflavin + ATP→FMN + ADP + H+
(EC 2.7.1.26)
mRNA_930 (9298)
FMN + dioxygen→8-demethyl-8-formylriboflavin 5'-phosphate + H2O (EC 2.6.1.114)
No genes
8-demethyl-8-formylriboflavin 5'-phosphate + an oxidized unknown electron carrier + H2O→8-carboxy-8-demethylriboflavin 5'-phosphate + a reduced unknown two electron carrier + H+ (EC 2.6.1.114)
No genes
8-carboxy-8-demethylriboflavin 5'-phosphate + 2 an oxidized unknown electron carrier + L-glutamate + H2O→8-amino-8-demethylriboflavin 5'-phosphate + 2-oxoglutarate + CO2 + 2 a reduced unknown two electron carrier (EC 2.6.1.114)
No genes
8-amino-8-demethylriboflavin 5'-phosphate + H2O→8-amino-8-demethylriboflavin + phosphate
No genes
8-amino-8-demethylriboflavin + S-adenosyl-L-methionine→8-demethyl-8-(methylamino)riboflavin + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.343)
No genes
8-demethyl-8-(methylamino)riboflavin + S-adenosyl-L-methionine→roseoflavin + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.343)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information