MetaCyc Pathway: pinoresinol degradation in Rhodosporidium toruloides IFO0880

Add experiment(s):


(+)-pinoresinol + 2 an oxidized azurin + H2O→(+)-6-hydroxypinoresinol + 2 H+ + 2 a reduced azurin (EC 1.17.9.2)
No genes
(+)-6-hydroxypinoresinol + an oxidized unknown electron carrier + H2O→4-(4-hydroxy-3-methoxyphenyl)-tetrahydro-3H-furo[3,4-c]furan-1-one + 2-methoxyhydroquinone + a reduced unknown two electron carrier
No genes
4-(4-hydroxy-3-methoxyphenyl)-tetrahydro-3H-furo[3,4-c]furan-1-one + an oxidized unknown electron carrier + H2O→4-hydroxy-4-(4-hydroxy-3-methoxyphenyl)-tetrahydrofuro[3,4-c]furan-1-one + a reduced unknown two electron carrier
No genes
4-(4-hydroxy-3-methoxyphenyl)-tetrahydro-3H-furo[3,4-c]furan-1-one + H2O→5-(4-hydroxy-3-methoxyphenyl)-4-(hydroxymethyl)oxolane-3-carboxylate + H+
No genes
2-methoxyhydroquinone + dioxygen→(2Z,4E)-4-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate + H+ (EC 1.13.11.66)
No genes
5-(4-hydroxy-3-methoxyphenyl)-4-(hydroxymethyl)oxolane-3-carboxylate→vanillin + an unknown compound
No genes
4-hydroxy-4-(4-hydroxy-3-methoxyphenyl)-tetrahydrofuro[3,4-c]furan-1-one→vanillin + an unknown compound
No genes
(2Z,4E)-4-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate→2-maleylacetate
No genes
Vanillin dehydrogenase:
vanillin + NAD+ + H2O→vanillate + NADH + 2 H+ (EC 1.2.1.67)
No genes
Maleylacetate reductase (in reverse):
2-maleylacetate + NAD(P)H + H+→3-oxoadipate + NAD(P)+ (EC 1.3.1.32)
mRNA_3939 (12307)
mRNA_733 (9101)

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information