MetaCyc Pathway: L-leucine degradation V (oxidative Stickland reaction) in Rhodosporidium toruloides IFO0880

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Branched-chain-amino-acid transaminase:
L-leucine + 2-oxoglutarate→4-methyl-2-oxopentanoate + L-glutamate
(EC 2.6.1.42; 2.6.1.6)
mRNA_5646 (14014)
mRNA_6242 (14610)
mRNA_6485 (14853)
3-methyl-2-oxobutanoate dehydrogenase (ferredoxin):
4-methyl-2-oxopentanoate + coenzyme A + 2 an oxidized ferredoxin [iron-sulfur] cluster→3-methylbutanoyl-CoA + CO2 + H+ + 2 a reduced ferredoxin [iron-sulfur] cluster
(EC 1.2.7.7)
No genes
3-methylbutanoyl-CoA + H2O→3-methylbutanoate + coenzyme A + H+
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information