MetaCyc Pathway: ubiquinol-6 biosynthesis (late decarboxylation) in Rhodosporidium toruloides IFO0880

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4-hydroxybenzoate nonaprenyltransferase:
4-hydroxybenzoate + all-trans-hexaprenyl diphosphate→4-hydroxy-3-hexaprenylbenzoate + diphosphate (EC 2.5.1.39)
mRNA_6869 (15237)
4-hydroxy-3-hexaprenylbenzoate + dioxygen + 2 H+ + 2 a reduced ferredoxin [iron-sulfur] cluster→3-all trans-hexaprenyl-4,5-dihydroxybenzoate + 2 an oxidized ferredoxin [iron-sulfur] cluster + H2O (EC 1.14.15.M7)
No genes
Hexaprenyldihydroxybenzoate methyltransferase:
3-all trans-hexaprenyl-4,5-dihydroxybenzoate + S-adenosyl-L-methionine→3-all trans-hexaprenyl-4-hydroxy-5-methoxybenzoate + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.114)
No genes
3-all trans-hexaprenyl-4-hydroxy-5-methoxybenzoate + H+→2-all trans-hexaprenyl-6-methoxyphenol + CO2
No genes
2-all trans-hexaprenyl-6-methoxyphenol + NADPH + dioxygen + H+→2-all trans-hexaprenyl-6-methoxyhydroquinone + NADP+ + H2O
No genes
2-all trans-hexaprenyl-6-methoxyhydroquinone + S-adenosyl-L-methionine→2-all-trans-hexaprenyl-6-methoxy-3-methyl-1,4-benzoquinol + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.201)
No genes
2-all-trans-hexaprenyl-6-methoxy-3-methyl-1,4-benzoquinol + a reduced unknown two electron carrier + dioxygen→3-demethylubiquinol-6 + an oxidized unknown electron carrier + H2O (EC 1.14.99.60)
No genes
3-demethylubiquinone-9 3-O-methyltransferase:
3-demethylubiquinol-6 + S-adenosyl-L-methionine→ubiquinol-6 + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.64)
mRNA_3097 (11465)

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information